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冷凝水闪蒸 2

仿生 1

分级转化；梯级利用；节能减排；煤炭 1

喷雾干燥 1

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Design and application of a novel coal-fired drum boiler using saline water in heavy oil recovery

Junping GU, Yuxin WU, Liping WU, Man ZHANG, Hairui YANG, Junfu LYU

《能源前沿（英文）》 2020年第14卷第4期页码 715-725 doi: 10.1007/s11708-020-0690-3

摘要： In this paper, the design and operation of a novel coal-fired circulating fluidized bed (CFB) drum boiler that can generate superheated steam using saline water were introduced. The natural circulation water dynamics with a drum was adopted instead of the traditional once-through steam generator (OTSG) design, so that superheated steam can be generated for the better performance of the steam assisted gravity drainage (SAGD) technology in heavy oil recovery. The optimized staged evaporation method was proposed to further decrease the salinity of water in the clean water section of the boiler. The evaporating pipes of the salted water section were rearranged in the back pass of the boiler, where the heat load is low, to further improve the heat transfer safety. A CFB combustion technology was used for coal firing to achieve a uniform heat transfer condition with low heat flux. Pollutant control technologies were adopted to reduce pollutant emissions. Based on the field test, the recommended water standard for the coal-fired CFB drum boilers was determined. With the present technology, the treated recovery wastewater can be reused in steam-injection boilers to generate superheated steam. The engineering applications show that the boiler efficiency is higher than 90%, the blowdown rate is limited within 5.5%, and the superheat of steam can reach up to 30 K. Besides, the heavy oil recovery efficiency is significantly improved. Moreover, the pollutant emissions of SO , NO and dust are controlled within the ranges of 20–90 mg/(N·m ), 30–90 mg/(N·m ) and 2–10 mg/(N·m ) respectively.

关键词： drum steam injection boiler natural circulation recovery wastewater staged evaporation circulating fluidized bed (CFB)

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Thin-liquid-film evaporation at contact line

Hao WANG, Zhenai PAN, Zhao CHEN

《能源前沿（英文）》 2009年第3卷第2期页码 141-151 doi: 10.1007/s11708-009-0020-2

摘要： When a liquid wets a solid wall, the extended meniscus near the contact line may be divided into three regions: a nonevaporating region, where the liquid is adsorbed on the wall; a transition region or thin-film region, where effects of long-range molecular forces (disjoining pressure) are felt; and an intrinsic meniscus region, where capillary forces dominate. The thin liquid film, with thickness from nanometers up to micrometers, covering the transition region and part of intrinsic meniscus, is gaining interest due to its high heat transfer rates. In this paper, a review was made of the researches on thin-liquid-film evaporation. The major characteristics of thin film, thin-film modeling based on continuum theory, simulations based on molecular dynamics, and thin-film profile and temperature measurements were summarized.

关键词： meniscus thin film contact line disjoining pressure evaporation

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Caloric evaporation of the brine in Zangnan Salt Lake

Shiqiang WANG, Yafei GUO, Nan ZHANG, Lingzhong BU, Tianlong DENG, Mianping ZHENG

《化学科学与工程前沿（英文）》 2011年第5卷第3期页码 343-348 doi: 10.1007/s11705-010-1029-0

摘要： Zangnan Salt Lake on the south of the Tibet is a type of carbonate lake with high concentrations of lithium, boron, and potassium and obviously it differs from seawater in its chemical composition. An experimental simulation of the caloric evaporation of the lake’s brine was conducted by first freezing the brine and then performing isothermal evaporation at 288.15 K. The freezing path and the physicochemical properties of the brine were determined. The crystallization sequence was natron, hydrohalite, halite, sylvite, zabuyelite, trona, aphthitalite, thermonatrite, and borax. Rubidium and cesium salts did not crystallized out but concentrated in the mother solution. The physicochemical properties (density, refractive index, conductivity, and pH) of the liquid phase changed as the evaporation progressed. In the beginning of the evaporation processes, the concentration of potassium ions in the liquid phase gradually increased but later it decreased. A peak value of 55.21 g/L was obtained when the evaporation was 88% complete. When the mineral aphthitalite began to crystallize; the concentrations of B O , Li , Rb , and Cs gradually increased as the evaporation progressed. When the evaporation was 98% complete, their concentrations in the mother liquor were 40.77 g/L, 4.838 g/L, 400.17 mg/L and 31.95 mg/L, respectively. This essential fundamental study can provide an important reference for the comprehensive utilization of brines in Zangnan Salt Lake.

关键词： Zangnan Salt Lake evaporation crystallization path freezing

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NO_x and H₂S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

《能源前沿（英文）》 2021年第15卷第1期页码 4-13 doi: 10.1007/s11708-020-0804-y

摘要： Low NO combustion of blended coals is widely used in coal-fired boilers in China to control NO emission; thus, it is necessary to understand the formation mechanism of NO and H S during the combustion of blended coals. This paper focused on the investigation of reductive gases in the formation of NO and H S in the reductive zone of blended coals during combustion. Experiments with Zhundong (ZD) and Commercial (GE) coal and their blends with different mixing ratios were conducted in a drop tube furnace at 1200°C–1400°C with an excessive air ratio of 0.6–1.2. The coal conversion and formation characteristics of CO, H S, and NO in the fuel-rich zone were carefully studied under different experimental conditions for different blend ratios. Blending ZD into GE was found to increase not only the coal conversion but also the concentrations of CO and H S as NO reduction accelerated. Both the CO and H S concentrations inblended coal combustion increase with an increase in the combustion temperature and a decrease in the excessive air ratio. Based on accumulated experimental data, one interesting finding was that NO and H S from blended coal combustion were almost directly dependent on the CO concentration, and the CO concentration of the blended coal combustion depended on the single char gasification conversion.Thus, CO, NO , and H S formation characteristics from blended coal combustion can be well predicted by single char gasification kinetics.

关键词： blended coal combustion NO_xformation H₂S formation air staged combustion

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基于煤炭分级转化的发电技术前景

岑可法,倪明江,骆仲泱,方梦祥,王勤辉,王智化,岑建孟

《中国工程科学》 2015年第17卷第9期页码 118-122

摘要：

面对我国一次能源以煤为主、能源需求日益增长以及大气环境持续恶化的现实，构建资源、能源、环境一体化的可持续发展能源系统是我国能源的战略方向。本文介绍了基于“煤炭既是能源又是资源”的理念提出的煤炭转化利用新技术——煤炭分级转化发电技术的路线和特点。从节能减排等方面对该技术的发展前景进行了展望，指出煤炭分级转化的发电技术可提高煤炭发电的综合效益，改变煤炭单一用于发电的产业结构，可形成基于煤炭资源化利用发电的新产业链并缓解我国油气等资源的紧缺状况，对于改变和优化国家煤电产业结构、循环经济和节能减排具有重要意义。

关键词：分级转化；梯级利用；节能减排；煤炭

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有固相析出的多效两段蒸发系统模型与过程模拟

李玲,阮奇

《中国工程科学》 2008年第10卷第10期页码 54-60

摘要：

建立了带有冷凝水闪蒸的有固相析出的多效两段蒸发系统的常规设计数学模型，模型将系统的相平衡关系用回归式表达，使模型可以用计算机编程求解，避免了手工计算结合查相图的烦琐的计算过程；利用矩阵方程具有结构清晰和高度模块化的特点，将系统的物料衡算和热量衡算方程组写成矩阵方程的形式，只要保留或舍弃矩阵方程中的相关块矩阵，模型就能代表没有冷凝水闪蒸或没有固相析出的多效两段蒸发系统常规设计模型；采用迭代法结合矩阵法来求解模型，算例表明，冷凝水闪蒸对多效两段蒸发系统是有效的节能措施，算法收敛速度快、收敛稳定性好。

关键词：固相析出多效两段蒸发数学模型冷凝水闪蒸

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A Review on Shale Gas Development in Fuling

Zhi-gang Wang

《工程管理前沿（英文）》 2015年第2卷第1期页码 76-81 doi: 10.15302/J-FEM-2015011

摘要： The Fuling Marine Shale Deposit contains vast gas resources. Due to tectonic activities, complex surface and geological conditions, significant differences make it unlike that of North America. Thus, it is not suitable to completely copy the technology and the development model from North America. Therefore we need engineering technology and a business development model fit for Fuling Shale Gas Development (FSGD). Through difficulties and characteristics analysis of the shale gas development area, we determined geological engineering design methods and integrated workflow, established a series of the core technologies, including horizontal well drilling with long laterals, staged fracturing and completion technology, developed main fluids, tools and equipment, put forward “well factory” mode in mountain region and “full cycle learning and system optimization” management methods. Break through was made in China’s first large-scale shale gas fields commercial development. By the end of 2014, production capacity reached 25 × 10 m /a, and cumulative gas production reached 12.24 × 10 m , which made a solid foundation to build production capacity of 50 × 10 m /a in 2015 and 100 × 10 m /a in 2017. Not only has FSGD established a demonstration for the other shale gas fields’ development, but also will be taken as reference to other large and extra-large construction projects of the industry.

关键词： Fuling shale gas drilling and completion staged fracturing learning curve capacity building commercial development

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A novel cryogenic insulation system of hollow glass microspheres and self-evaporation vapor-cooled shield

Jianpeng ZHENG, Liubiao CHEN, Ping WANG, Jingjie ZHANG, Junjie WANG, Yuan ZHOU

《能源前沿（英文）》 2020年第14卷第3期页码 570-577 doi: 10.1007/s11708-019-0642-y

摘要： Liquid hydrogen (LH ) attracts widespread attention because of its highest energy storage density. However, evaporation loss is a serious problem in LH storage due to the low boiling point (20 K). Efficient insulation technology is an important issue in the study of LH storage. Hollow glass microspheres (HGMs) is a potential promising thermal insulation material because of its low apparent thermal conductivity, fast installation (Compared with multi-layer insulation, it can be injected in a short time.), and easy maintenance. A novel cryogenic insulation system consisting of HGMs and a self-evaporating vapor-cooled shield (VCS) is proposed for storage of LH . A thermodynamic model has been established to analyze the coupled heat transfer characteristics of HGMs and VCS in the composite insulation system. The results show that the combination of HGMs and VCS can effectively reduce heat flux into the LH tank. With the increase of VCS number from 1 to 3, the minimum heat flux through HGMs decreases by 57.36%, 65.29%, and 68.21%, respectively. Another significant advantage of HGMs is that their thermal insulation properties are not sensitive to ambient vacuum change. When ambient vacuum rises from 10 Pa to 1 Pa, the heat flux into the LH tank increases by approximately 20%. When the vacuum rises from 10 Pa to 100 Pa, the combination of VCS and HGMs reduces the heat flux into the tank by 58.08%–69.84% compared with pure HGMs.

关键词： liquid hydrogen storage hollow glass microspheres (HGMs) self-evaporation vapor-cooled shield (VCS) thermodynamic optimization

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Effect of soil crust on evaporation and dew deposition in Mu Us sandy land, China

SUN Yongliang, LI Xiaoyan, XU Heye, YANG Zhipeng, TANG Jia, ZHANG Xiaoying

《环境科学与工程前沿（英文）》 2008年第2卷第4期页码 480-486 doi: 10.1007/s11783-008-0034-8

摘要： The development of soil crust on sandy land may affect the surface hydrological process. This paper investigates the process of evaporation and dew deposition influenced by different soil surface types which were dominated by sand, primitive biotic crust, and advanced biotic crust, respectively, in the south fringe of Mu Us sandy land in Northwest China from July to September of 2006. The experimental results indicate that the advanced biotic crust could increase evaporation and dew deposition compared to the primitive biotic crust and bare sand although the differences between them were not significant. The average evaporation from advanced biotic crust, primitive biotic crust and sand was 6.8, 6.6, and 6.5 mm/d, respectively, and water content is around 16.2 % in the condition of initially identical soil. The average dew amount on advanced biotic crust was 0.116 mm/d with extreme 0.05 and 0.24 mm/d. The average values on primitive biotic crust and sand were 0.105 and 0.101 mm/d, respectively, with extreme 0.04 and 0.21 mm/d for both treatments. Also, the dew deposition on advanced biotic crust seemed stable and might rest for a longer time than that on primitive biotic crust and sand. The results suggest that the advanced biotic crust possibly facilitates evaporation and dew deposition. Therefore, the development of biotic crust may potentially enhance the hydrological circulation in the upper sand layer in sandy land.

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Heat and mass transfer of ammonia-water in falling film evaporator

Xianbiao BU, Weibin MA, Huashan LI

《能源前沿（英文）》 2011年第5卷第4期页码 358-366 doi: 10.1007/s11708-011-0161-y

摘要： To investigate the performance of heat and mass transfer of ammonia-water during the process of falling film evaporation in vertical tube evaporator, a mathematical model of evaporation process was presented, the solution of which that needed a coordinate transformation was based on stream function. The computational results from the mathematical model were validated with experimental data. Subsequently, a series of parameters, such as velocity, film thickness and concentration, etc., were obtained from the mathematical model. Calculated results show that the average velocity and the film thickness change dramatically at the entrance region when <100 mm, while they vary slightly with the tube length in the fully developed region when >100 mm. The average concentration of the solution reduces along the tube length because of evaporation, but the reducing tendency becomes slow. It can be concluded that there is an optimalβrelationship between the tube length and the electricity generated. The reason for the bigger concentration gradient in the direction is that the smooth tube is chosen in the calculation. It is suggested that the roll-worked enhanced tube or other enhanced tube can reduce the concentration gradient in the film thickness direction and enhance the heat and mass transfer rate.

关键词： falling film evaporation ammonia-water heat and mass transfer

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Improved film evaporator for mechanistic understanding of microwave-induced separation process

Xin Gao, Dandan Shu, Xingang Li, Hong Li

《化学科学与工程前沿（英文）》 2019年第13卷第4期页码 759-771 doi: 10.1007/s11705-019-1816-1

摘要： Microwave-induced film evaporation separation process has been reported recently to separate the polar/nonpolar mixture. However, the efficiency of the separation is still too low for practical applications, which requires further enhancement via different strategies such as optimization design of evaporator structure. In addition the depth understanding of the separation mechanisms is great importance for better utilization of the microwave-induced separation process. To carry out these investigations, a novel microwave-induced falling film evaporation instrument was developed in this paper. The improvement of the enhancement effect of microwave-induced separation was observed based on the improved film evaporator. The systematic experiments on microwave-induced separation with different binary azeotropic mixtures (ethanol-ethyl acetate system and dimethyl carbonate (DMC)-H O system) were conducted based on the new evaporator. For the ethanol-ethyl acetate system, microwave irradiation shift the direction of evaporation separation at higher ethanol content in the starting liquid mixture. Moreover, for DMC-H O system microwave-induced separation process broke through the limitations of the traditional distillation process. The results clearly demonstrated the microwave-induced evaporation separation process could be commendably applied to the separation of binary azeotrope with different dielectric properties. Effects of operating parameters are also investigated to trigger further mechanism understanding on the microwave-induced separation process.

关键词： process intensification microwave falling film evaporation separation azeotrope

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复杂并流多效蒸发系统的数学模型与矩阵解法

阮奇,陈文波,黄诗煌,叶长燊

《中国工程科学》 2001年第3卷第4期页码 36-41

摘要：

建立了有冷凝水闪蒸和额外蒸汽引出的复杂并流多效蒸发系统的数学模型, 常规并流多效蒸发模型只是该模型的一个特例。提出一种新算法--迭代法结合矩阵法求解模型并给出算法框图。算例表明新算法比常用的牛顿迭代法和Broyden法效率更高，具有对初值要求不高、收敛稳定性好、收敛速度快等优点。对三效并流蒸发蔗糖水溶液系统，采用冷凝水闪蒸和引出额外蒸汽将原料液从26.7 ℃预热至90 ℃，约可节省16%的加热生蒸汽，节能效果显著。

关键词：冷凝水闪蒸额外蒸汽引出并流流程多效蒸发数学模型矩阵解法

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Chemical speciation and anthropogenic sources of ambient volatile organic compounds (VOCs) during summer in Beijing, 2004

LU Sihua, LIU Ying, SHAO Min, HUANG Shan

《环境科学与工程前沿（英文）》 2007年第1卷第2期页码 147-152 doi: 10.1007/s11783-007-0026-0

摘要： Volatile organic compounds (VOCs) were measured at six sites in Beijing in August, 2004. Up to 148 VOC species, including C to C alkanes, C to C alkenes, C to C aromatics, and halogenated hydrocarbons, were quantified. Although the concentrations differed at the sites, the chemical compositions were similar, except for the Tongzhou site where aromatics were significantly high in the air. Based on the source profiles measured from previous studies, the source apportionment of ambient VOCs was preformed by deploying the chemical mass balance (CMB) model. The results show that urban VOCs are predominant from mobile source emissions, which contribute more than 50% of the VOCs (in mass concentrations) to ambient air at most sites. Other important sources are gasoline evaporation, painting, and solvents. The exception is at the Tongzhou site where vehicle exhaust, painting, and solvents have about equal contribution, around 35% of the ambient VOC concentration. As the receptor model is not valid for deriving the sources of reactive species, such as isoprene and 1,3-butadiene, other methodologies need to be further explored.

关键词： Beijing exception gasoline evaporation August exhaust

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Experimental study on film combustion formed by spirally fluted horizontal tube

MEI Ning, ZHANG Bin, ZHAO Jian, ZHANG Ming

《能源前沿（英文）》 2008年第2卷第1期页码 54-58 doi: 10.1007/s11708-008-0023-4

摘要： Falling fuel film on the spirally fluted surface of a horizontal tube can provide rapid fuel evaporation and homogeneous mixture formation. This fuel film combustion could be applied in a micro-combustion system even without a fuel pump. A test bed was established and experimental comparisons were made between the prototype and a transferred cup atomizer micro-combustor. The theoretical and experimental results show that film combustion has a higher combustion efficiency, a lower pollutant emission and a better working performance.

关键词： homogeneous transferred evaporation micro-combustion efficiency